by Takafumi Maeda, Tobias Hemsel, Takeshi Morita
Abstract:
In this study, we report some improvements in a hydrothermal method for lead-free piezoelectric powders and the performance of the sintered (K$_0.48$Na$_0.52$)NbO$_3$ ceramics. To increase the obtained powder weight per source solution volume, the hydrothermal reaction conditions were modified. This improvement is important for mass production; however, it resulted in a larger particle size dispersion. Therefore, we examined to introduced the ball milling process that is useful for dense (K$_0.48$Na$_0.52$)NbO$_3$ ceramics. When a large amount of powder was obtained, it took a long time to eliminate the residual alkaline ions in the hydrothermal powders by a washing process. Therefore, a neutralization was conducted in the powder washing process. Using this powder, a solid solution of (K,Na)NbO$_3$ceramics was synthesized. The relative density was successfully increased. Concerning the electrical properties, the relative permittivity was improved, and the piezoelectric constant d$_33$ was also increased from 114 to 130 pC/N.
Reference:
Maeda, T.; Hemsel, T.; Morita, T.: Improved Process for Hydrothermal Lead-Free Piezoelectric Powders and Performances of Sintered (K0.48Na0.52)NbO3 Ceramics. Japanese Journal of Applied Physics, The Japan Society of Applied Physics, volume 50, 2011.
Bibtex Entry:
@ARTICLE{Maeda2011,
author = {Takafumi Maeda and Tobias Hemsel and Takeshi Morita},
title = {Improved Process for Hydrothermal Lead-Free Piezoelectric Powders
and Performances of Sintered (K0.48Na0.52)NbO3 Ceramics},
journal = {Japanese Journal of Applied Physics},
year = {2011},
volume = {50},
pages = {07HC01},
abstract = {In this study, we report some improvements in a hydrothermal method
for lead-free piezoelectric powders and the performance of the sintered
(K$_{0.48}$Na$_{0.52}$)NbO$_{3}$ ceramics. To increase the obtained
powder weight per source solution volume, the hydrothermal reaction
conditions were modified. This improvement is important for mass
production; however, it resulted in a larger particle size dispersion.
Therefore, we examined to introduced the ball milling process that
is useful for dense (K$_{0.48}$Na$_{0.52}$)NbO$_{3}$ ceramics. When
a large amount of powder was obtained, it took a long time to eliminate
the residual alkaline ions in the hydrothermal powders by a washing
process. Therefore, a neutralization was conducted in the powder
washing process. Using this powder, a solid solution of (K,Na)NbO$_{3}$ceramics
was synthesized. The relative density was successfully increased.
Concerning the electrical properties, the relative permittivity was
improved, and the piezoelectric constant d$_{33}$ was also increased
from 114 to 130 pC/N.},
bdsk-url-1 = {http://www.ems.k.u-tokyo.ac.jp/morita/Papers/56_maeda_JJAP.pdf},
file = {Maeda2011.pdf:Maeda2011.pdf:PDF},
numpages = {4},
publisher = {The Japan Society of Applied Physics},
timestamp = {2013.09.26},
url = {http://www.ems.k.u-tokyo.ac.jp/morita/Papers/56_maeda_JJAP.pdf}
}